HIDROCARBONETOS POLICÍCLICOS AROMÁTICOS ATMOSFÉRICOS DE FONTES AUTOMOTIVAS: UMA BREVE REVISÃO

Autores

  • Julie Anne Holanda Azevedo Instituto Federal do Ceará
  • Rinaldo dos Santos Araújo Instituto Federal do Ceará
  • Glória Maria Marinho Silva Instituto Federal do Ceará

DOI:

https://doi.org/10.15628/holos.2013.1234

Resumo

A ocorrência de hidrocarbonetos policíclicos aromáticos (HPAs) no ambiente tem se tornado preocupante por serem estes compostos possíveis agentes cancerígenos humanos. HPAs e seus derivados são produzidos pela combustão incompleta da matéria orgânica, sendo a queima de combustíveis fósseis uma das principais fontes desses poluentes no meio ambiente. As concentrações de HPAs aumentam significativamente em ambientes urbanos e são influenciadas principalmente por emissões veiculares. Os HPAs são encontrados em fase gasosa a baixos níveis, porém na maioria encontram-se associado às partículas finas em suspensão no ar atmosférico. Esta revisão descreve os HPAs provenientes de emissões veiculares quanto as suas características de amostragem e análise, identificação, legislação e saúde ambiental. Oportunamente, alguns países propõem limites de concentração não obrigatórios para os HPAs, porém muitos estudos relacionados à exposição a estes compostos mostram que estes poluentes devem ser prioritários quando se considera a qualidade do ar e o risco à saúde humana.

Downloads

Não há dados estatísticos.

Referências

Ravindra, K.; Mital, A. K.; Grieken, R. van. Health Risk Assessment of Urban Suspended Particulate Matter with Special Reference to Polycyclic Aromatic Hydrocarbons: A Review. Review on Environmental Health, v.16, p.169-189, 2001.

Meador, J. P.; Casillas, E.; Sloan, C. A.; Varanasi, U. Comparative bioaccumulation of polycyclic aromatic hydrocarbons from sediment by two infaunal invertebrates. Marine Ecology Progress Series, v.123, p.107-124, 1995.

Agency for Toxic Substances and Disease Registry (ATRSD). Polycyclic aromatic hydrocarbons (PAHs). US Department of Health and Human Services, Public Health Service. Atlanta, 1996.

Agency for Toxic Substances and Disease Registry (ATRSD). Support document to the 2011 priority list of hazardous substances that will be the subject of toxicological profiles. Division of Toxicology and Environmental Medicine, Atlanta, 2011.

Environmental Protection Agency (EPA). Peer review and peer involvement at the US Environmental Protection Agency, Science Policy Council, Office of the Science Advisor, Environmental Protection Agency, 1994.

Ravindra, K.; Sokh, R.; Grieken, R. van. Atmospheric polycyclic aromatic hydrocarbons: Source attribution, emission factors and regulation. Atmospheric Environment, v.42, p.2895-2921, 2008.

Bojes, H. K.; Pope, P. G. Characterization of EPA's 16 priority pollutant polycyclic aromatic hydrocarbons (PAHs) in tank bottom solids and associated contaminated soils at oil exploration and production sites in Texas. Regulatory Toxicology and Pharmacology, v.47, p.288-295, 2007.

Tavares Júnior, M.; Pinto, J. P.; Souza, A. L.; Scarmínio, I. S.; Solci, M. C. Emission of polycyclic aromatic hydrocarbons from diesel engine in a bus station, Londrina, Brazil. Atmospheric Environment, v.38, p.5039-5044, 2004.

Fernandes, M. B.; Brickus, L. S. R.; Moreira, J. C.; Cardoso, J. N. Atmosferic BTX and polyaromatic hydrocarbons in Rio de Janeiro, Brazil. Chemosphere, v.47, p.417-425, 2002.

Rogge, W. F.; Hildemann, L. M.; Mazurek, M. A.; Cass, G. R. Sources of fine organic aerosol. 9. Pine, oak, and synthetic log combustion in residential fireplaces. Environment Science Technology, v.32, p.13-22, 1998.

Pistikopoulos, P.; Masclet, P.; Mouvier, G. A receptor model adapted to reactive species: polycyclic aromatic hydrocarbons; evaluation of source contributions in an open urban site-I. Particle compounds. Atmospheric Environment, v. 24A, n. 5, p.1189-1197, 1990.

Jenkins, B. M.; Jones, A. D.; Turn, S. Q.; Williams, R. B. Particle concentrations, gas-particle partitioning, and species intercorrelations for polycyclic aromatic hydrocarbons (PAH) emitted during biomass burning. Atmospheric Environment, v.30, n.22, p.3825-3835, 1996.

Rajput, N.; Lakhani, A. Measurements of polycyclic aromatic hydrocarbons in an urban atmosphere of Agra, India. Atmósfera, v.23, n.2, p.165-183, 2010.

Callén, M. S.; Cruz, M. T. de la; López, J. M.; Mastral, A. M. PAH in airborne particulate matter. Carcinogenic character of PM10 samples and assessment of the energy generation impact. Fuel Processing Technology, v.92, p.176-182, 2011.

Chow, J.C.; Waston, J. G.; Lowenthal, D. H.; Soloman, P. A.; Magliano, K. L.; Ziman, S. D.; Richards, L. W. PM10 and PM2.5 composition in California Sari Joaquin valley. Aersal Science and Technology, v.18, p.105-128, 1993.

Chow, J. C.; Watson, J. G.; Fujita, E. M.; Lu, Z. Q.; Oawson, D. R.; Ashbaugh, L. L. Temporal and spatial variation of PM2.5 and PM10 aerosol in the southern California air quality study. Atmospheric Environment, v.28, p.2061-2080, 1994.

Shane, B. S.; Henry, C. B.; Hotchkiss, J. H.; Klausner, K. A.; Gutenmann, W. H; Lisk, D. J. Organic toxicants and mutagens in ashes from eighteen municipal refuse incinerators. Arch Environ Contam Toxicol, v.19, n.5, p.665-673, 1990.

Klockow, D.; Targa, H. J. Performance and results of a six-year German/Brazilian research Project in the industrial área of Cubatão/SP, Brazil. Pure and Applied Chemistry, v.70, p.2287-2293, 1998.

Van Metre, P. C.; Mahler, B. J.; Furlong, E. T. Urban sprawl leaves its PAH signature. Environmental Science and Technology, v.34, p.4064-4070, 2000.

Baek, S. O.; Field, R. A.; Goldstone, M. E.; Kirk, P. W.; Lester, J. N.; Perry, R. A review of atmospheric polycyclic aromatic hydrocarbons: sources, fate and behavior. Water, Air and Soil Pollution, v.60, p.279-300, 1991.

Allen, A. G.; Rocha, G. O. da.; Cardoso, A. A.; Machado, C. M. D.; Andrade, J. B. de. Atmospheric particulate polycyclic aromatic hydrocarbons from road transport in southeast Brazil. Transportation Research, Part D, v.13, p.483-490, 2008.

Chen, Y. C.; Lee, W. J.; Uang, S. N.; Lee, S. H.; Tsai, P. J. Characteristics of polycyclic aromatic hydrocarbon (PAH) emissions from a UH-1H helicopter engine and its impact on the ambient environment. Atmospheric Environment, v.40, p.7589-7597, 2006.

Cooper, D. A. Exhaust emissions from high speed passenger ferries. Atmospheric Environment, v.35, p.4189-4200, 2001.

Cooper, D.A. Exhaust emissions from ships at berth. Atmospheric Environment, v.37, p.3817-3830, 2003.

Devos, O.; Combet, E.; Tassel, P.; Paturel, L. Exhaust emissions of PAHs of passenger cars. Polycyclic Aromatic Compounds, v.26, p.69-78, 2006.

Rojas, N. Y.; Milquez, H. A.; Sarmiento, H. Characterizing priority polycyclic aromatic hydrocarbons (PAH) in particulate matter from diesel and palm oil-based biodiesel B15 combustion. Atmospheric Environment, v.45, p.6158-6162, 2011.

Marr, L. C.; Kirchstetter, T. W.; Harley, R. A. Characterization of polycyclic aromatic hydrocarbons in motor vehicle fuels and exhaust emissions. Environment Science Technology, v.33, p.3091-3099, 1999.

Alkurdi, F.; Karabet, F.; Dimashki, M. Characterization, concentrations and emission rates of polycyclic aromatic hydrocarbons in the exhaust emissions from in-service vehicles in Damascus. Atmospheric Research, v.120-121, p.68-77, 2013.

Jones, C. C.; Chughtai, A. R.; Murugaverl, B.; Smith, D. M. Effects of air/fuel combustion ratio on the polycyclic aromatic hydrocarbon content of carbonaceous soots from select fuels. Carbon, v.42, p.2471-2484, 2004.

Brasser, L. J. Polycyclic aromatic hydrocarbon concentrations in the Netherlands. VDI-Berichte, v.348, p.171-180, 1980.

Hooper, M. A.; Body, P. J.; Hooper, B. M. Coal Liquefaction: Atmospheric Impacts: a Final Report to the Coal Corporation of Victoria. Gippsland Centre for Environmental Science, Monash University, Gippsland, 1993.

Smith, D. J. T.; Harrison, R. M. Polycyclic aromatic hydrocarbons in atmospheric particles. In: Harrison, R.M., Van Grieken, R. (Eds.). Atmospheric Particles, Wiley, 1998.

Ravindra, K.; Bencs, L.; Wauters, E.; Hoog, J. de.; Deutsch, F.; Roekens, E.; Bleux, N.; Berghmans, P.; Grieken, R. van. Seasonal and site-specific variation in vapour and aerosol phase PAHs over Flanders (Belgium) and their relation with anthropogenic activities. Atmospheric Environment, v.40, p.771-785, 2006.

Miguel, A. H.; Kirchstetter, T. W.; Harley, R. A. On-Road emissions of particulate polycyclic aromatic hydrocarbons and Black Carbon from Gasoline and diesel vehicles. Environment Science Technology, v.32, p.450-455, 1998.

Harrison, R. M.; Smith, D. J. T.; Luhana, L. Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, U.K. Environment Science Technology, v.30, p.825-832, 1996.

Stenberg, U.; Alsberg, T.; Blomberg, L.; Wannman, T. Gas chromatographic separation of high-molecular polynuclear aromatic hydrocarbons in samples from different sources, using temperature stable glass capillary columns. In: Jones, P.W., Leber, P. (Eds.), Polynuclear Aromatic Hydrocarbons, 3rd International Symposium. Ann Arbor Science, Ann Arbor, MI, p.313-326, 1979.

Mainwaring, S. J.; Stirling, D. M. A study of the size distribution and concentrations of polynuclear hydrocarbons in Melbourne air. In: Webb, K.A., Smith, A.J. (Eds.), Proceedings of the 7th International Clean Air Conference, Adelaide, Australia. Ann Arbor Science, Ann Arbor, MI, p.605-622, 1981.

Azimi, S.; Rocher, V.; Muller, M.; Moilleron, R.; Thevenot, D. R. Sources, distribution and variability of hydrocarbons and metals in atmospheric deposition in an urban area (Paris, France). Science of the Total Environment, v.337, p.223-239, 2005.

Manoli, E.; Vousta, D.; Samara, C. Chemical characterization and source identification/ apportionment of fine and coarse air particles in Thessaloniki, Greece. Atmospheric Environmental, v.36, p.949- 61, 2002.

Park, J. S.; Wade, T. L.; Sweet, S. Atmospheric distribution of polycyclic aromatic hydrocarbons and deposition to Galveston Bay, Texas, USA. Atmospheric Environment, v.35, p.3241-3249, 2001.

Lang, Q.; Zhang, Q.; Jaffé, R. Organic aerosols in the Miami area, USA: temporal variability of atmospheric particles and wet/dry deposition. Chemosphere, v.47, p.427- 441, 2002.

Khalili, N. R.; Scheff, P. A.; Holsen, T. M. PAH source fingerprints for cake ovens, diesel, and gasoline engines, highway tunnel, and wood combustion emissions. Atmospheric Environment, v.29, n.4, p.533-542, 1995.

Soclo, H. H.; Garrugues, P.; Ewald, M. Origin of polycyclic aromatic hydrocarbons (PAHs) in coastal marin sediments: case studies in Cotonou (Benin) and Aquitaine (France) areas. Mar Pollut Bull, v.40, p.387-396, 2000.

Moreda, J. M.; Arranz, A.; Fdez De Betono, S.; Cid, A.; Arranz, J. F. Chromatographic determination of aliphatic hydrocarbons and polyaromatic hydrocarbons (PAHs) in a sewage sludge. Science of the Total Environment, v.220, p.33-43, 1998.

De Martins, B. S.; Okamoto, R. A.; Kado, N. Y.; Gundel, L. A.; Carvalho, L. R. F. Polycyclic aromatic hydrocarbons in a bioassay-fractionated extract of PM10 collected is São Paulo, Brazil. Atmospheric Environment, v.36, p.307-314, 2002.

Vasconcellos, P. C.; Zacarias, D.; Pires, M. A. F.; Pool, C. S.; Carvalho, L. R. F. Measurements of polycyclic aromatic hydrocarbons in airborne particles from the metropolitan area of São Paulo City, Brazil. Atmospheric Environment, v.37, p.3009-3018, 2003.

Bourotte, C.; Forti, M. C.; Taniguchi, S.; Bícego, M. C.; Lotufo, P. A. A wintertime study of PAHs in fine and coarse aerosols in São Paulo city, Brazil. Atmospheric Environment, v.39, p.3799-3811, 2005.

Ré-Poppi, N.; Silva, M. S. Polycyclic aromatic hydrocarbons and other selected organic compounds in ambient air of Campo Grande City, Brazil. Atmospheric Environment, v.39, p.2839-2850, 2005.

Guo, H.; Lee, S. C.; Ho, K. F.; Wang, X. M.; Zou, S. C. Particle-associated polycyclic aromatic hydrocarbons in urban air of Hong Kong. Atmospheric Environment, v.37, p.5307-5317, 2003.

Liu, L-B.; Liu, Y.; Lin, J-M.; Tang, N.; Hayakawa, K.; Maeda, T. Development of analytical methods for polycyclic aromatic hydrocarbons (PAHs) in airborne particulates: A review. Journal of Environmental Sciences, v.19, p.1-11, 2007.

Anastasopoulos, A. T.; Wheeler, A. J.; Karman, D.; Kulka, R. H. Intraurban concentrations, spatial variability and correlation of ambient polycyclic aromatic hydrocarbons (PAH) and PM2.5. Atmospheric Environment, v.59, p.272-283, 2012.

Chen, Y.; Ho, K. F.; Hang Ho, S. S.; Kei Ho, W.; Lee, S. C.; Zhen Yu, J.; Sit, E. H. L. Gaseous and particulate polycyclic aromatic hydrocarbons (PAHs) emissions from commercial restaurants in Hong Kong. Journal of Environmental Monitoring, v.9, p.1402-1409, 2007.

Dejean, S.; Raynaud, C.; Meybeck, M.; Massa, J. P. D.; Simon, V. Polycyclic aromatic hydrocarbons (PAHs) in atmospheric urban area: monitoring on various types of sites. Environmental Monitoring and Assessment, v.148, p.27-37, 2009.

Menichini, E.; Iacovella, N.; Monfredini, F.; Turrio-Baldassarri, L. Relationships between indoor and outdoor air pollution by carcinogenic PAHs and PCBs. Atmospheric Environment, v.41, p.9518-9529, 2007.

Nelson, P. F.; Tibbett, A. R.; Day, S. J. Effects of vehicle type and fuel quality on real world toxic emissions from diesel vehicles. Atmospheric Environment, v.42, p.5291-5303, 2008.

Park, S. S.; Kim, Y. J.; Kang, C. H. Atmospheric polycyclic aromatic hydrocarbons in Seoul, Korea. Atmospheric Environment, v.36, p.2917-2924, 2002.

Cincinelli A.; Del Bubba M.; Martellini, T.; Gambaro A.; Lepri, L. Gas-particle concentration and distribution of n-alkanes and polycyclic aromatic hydrocarbons in the atmosphere of Prato (Italy). Chemosphere, v.68, p.472-478, 2007.

Gigliotti, C. L.; Totten, L. A.; Offenberg, J. H. Atmospheric concentrations and deposition of polycyclic aromatic hydrocarbons to the mid-atlantic east coast region. Environmental Science and Technology, v.39, p.5550-5559, 2005.

Oda, J.; Nomura, S.; Yasuhara, A.; Shibamoto, T. Mobile sources of atmospheric polycyclic aromatic hydrocarbons in a roadway tunnel. Atmospheric Environment, v.35, p.4819-4827, 2001.

Borrás, E.; Tortajada-Genaro, L. A. Characterisation of polycyclic aromatic hydrocarbons in atmospheric aerosols by gas chromatography-mass spectrometry. Analytica Chimica Acta, v.583, p.266-276, 2007.

Godoi, A. F. L.; Ravindra, K.; Godoi, R. H. M.; Andrade, S. J.; Santiago-Silva, M., Van Vaeck, L.; Van Grieken, R. Fast Chromatographic determination of polycyclic aromatic hydrocarbons in aerosol samples from sugar cane burning. Journal of Chromatography A, v.1027, p.49-53, 2004.

Karthikeyan, S.; Balasubramanian, R.; See, S.W. Optimization and validation of a low temperature microwave-assisted extraction method for analysis of polycyclic aromatic hydrocarbons in airborne particulate matter., Talanta, v.69, p.79-86, 2006.

Ho, K. F.; Ho, S. S. H.; Lee, S. C.; Cheng, Y.; Chow, J. C.; Watson, J. G.; Louie, P. K. K.; Tian, L. Emissions of gas- and particle-phase polycyclic aromatic hydrocarbons (PAHs) in the Shing Mun Tunnel, Hong Kong. Atmospheric Environment, v.43, p.6343-6351, 2009.

International Agency for Research on Cancer (IARC). Evaluations of carcinogenicity to humans. Some non-heterocyclic polycyclic aromatic hydrocarbons and some related exposures/IARC. Working Group on the Evaluation of Carcinogenic Risks to Humans (2005: Lyon, France), v.92, 2005.

Cerna, M.; Pochamanova, D.; Pastorkova, A.; Bene, I.; Lenicek, J.; Topinka, J.; Binkova, B. Genotoxicity of urban air pollutants in Czech Republic. Muation Research/Genetic Toxicology and Environmental Mutagenesis, v.469, n.1, p.71-82, 2000.

Durant, J. L.; Bushy, W. F.; Lafleur, A. L.; Penman, B. W.; Crespi, C. L. Human cell mutagenicity of oxygenated, nitrated and unsubstituted polycyclic aromatic hydrocarbons associated with urban aerosols. Mutation Research-Genetic Toxicology, v.371, n. 3-4, p.123-157, 1996.

Dutch National Institute of Public Health and the Environment (RIVM). Environmental risk limits in The Netherlands. Report no. 601640 001, 1999.

Dutch National Institute of Public Health and the Environment (RIVM). Setting integrated environmental quality standards: environmental quality standards for soil, water and air, 1999.

Agency for Toxic Substances and Disease Registry (ATSDR). Toxicological Profile for Polycyclic Aromatic Hydrocarbons. US Department of Health and Human Services, Public Health Service, 1995.

European Union Directive (EUD). Directive 2004/107/EC of the European parliament and of the council. Official Journal of European Union L23, p.3-16, 2004.

National Air Quality Information Archive (NAQIA). United Kingdom, 1999.

Paturel, L.; Saber, A.; Combet, E.; Joumard, R. Analysis of PAH emissions from passenger cars by high resolution Shpol'skii spectrofluorimetry. Polycyclic Aromatic Compounds, v.9, p.331-339, 1996.

Schauer, J. J.; Kleeman, M. J.; Cass, G. R.; Simoneit, B. R. T. Measurement of emissions from air pollution sources. 5. C1-C32 organic compounds from gasoline-powered motor vehicles. Environment Science Technology, v.36, p.1169-1180, 2002.

Rogge, W. F.; Mazurek, M. A.; Hildemann, L. M.; Cass, G. R. Quantification of urban organic aerosols at a molecular level: identification, abundance and seasonal variation. Atmospheric Environment, v.27A, n.8, p.1309-1330, 1993.

Ying, W.; Longbao, Z.; Hewu, W. Diesel emission improvements by the use of oxygenated DME/diesel blend fuels. Atmospheric Environment, v.40, p.2313-2320, 2006.

Westerholm, R.; Alsberg, T.; Frommelin, A.; Strandell, M.; Rannug, U.; Winquist, L.; Grigoriadis, V.; Egebäck, K. -E. Effect of fuel polycyclic aromatic hydrocarbon content on the emissions of polycyclic aromatic hydrocarbons and other mutagenic substances from a gasoline-fueled automobile. Environmental Science and Technology, v.22, p.925-930, 1988.

Downloads

Publicado

17/03/2013

Como Citar

Azevedo, J. A. H., Araújo, R. dos S., & Silva, G. M. M. (2013). HIDROCARBONETOS POLICÍCLICOS AROMÁTICOS ATMOSFÉRICOS DE FONTES AUTOMOTIVAS: UMA BREVE REVISÃO. HOLOS, 1, 102–114. https://doi.org/10.15628/holos.2013.1234

Edição

Seção

ARTIGOS

Artigos mais lidos pelo mesmo(s) autor(es)